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High temperature resistance 370℃ FFKM

370℃ ClassFluoropower FFSG_Sakura Seal O-ring.png FFKM 

Fluoro-Power FFSG (Fluoro-Power FFSG / FP-FFSG) is a rubber material for O-rings with heat resistance, which is the highest in the world at 370 ℃ class . Various FFKM (perflo) materials, which are considered to be synonymous with high-performance fluororubber , are the flagship of the Fluoro-Power® series due to their excellent chemical resistance as well as heat resistance. It is an advanced polymer compoundthat bears the burden of. Is their raw materials " perfluoroelastomer ( FFKM) to" Nippon Zeon tip material in cooperation with "SGCNT (see Super Growth single-walled Carbon Nanotube = SWNTs / or below supergrowth Method)" It is this Fluoropower FF SG that has succeeded in blending. The encounter of the art, which has played a vertex to as a choice in a high temperature range fluoroalkyl power FFS and fluoroalkyl power FFSW grade refractory grade surpassing the birth, we Ainari and the limit value of the rubber material is increased updated rice field.



About "SGCNT" from Japan
CNT is a kind of allotrope made of carbon, "Carbon Nanotube". Nanomaterials (materials with a particle size of 100 nm or less. 1 nm = 1 nanometer is 10-9 meters, that is, one billionth of a meter), which is considered to be the next-generation carbon material . It is classified into carbon nanotubes (Single-Walled Carbon Nanotube) and MWCNTs (multi-Walled Carbon Nanotubes). The "CNT" of "SGCNT" used in Fluoropower FFSG is SWCNT. SWCNTs have the characteristics of high thermal and electrical conductivity and high strength, and they play an important role in supporting the outstanding heat resistance of Fluoropower FFSG. "SG" in "SGCNT" is a CVD method developed by AIST (National Institute of Advanced Industrial Science and Technology) based on the results of the NEDO (New Energy and Industrial Technology Development Organization) project. It represents one of the (methods of thermally decomposing nanoparticles of catalyst metal and hydrocarbons to obtain CNTs), "a Super Growth method". Although CNT (SWCNT) has rare properties, it is also a material that is difficult to exceed the range of applications for academic research because it requires a large amount of cost for synthesis. The super growth method is what brought the cost closer to a practical level. This epoch-making synthesis technology dramatically extends the life of the catalyst in the synthetic atmosphere by adding a very small amount of water, which makes it possible to produce a large amount of CNT (SWCNT) with 3,000 times the time efficiency of the conventional one. I did. However, SGCNT is still expensive to use as a compounding material for rubber products and is a rubber compound.In the manufacturing process of, there are still many problems such as the need for special technology to uniformly disperse in polymers such as perfluoroelastomer (FFKM). However, I strongly hope that SGCNT and Fluoropower FFSG, spun by Japanese science and technology, will be able to illuminate a wide range of industries and research fields around the world beyond Japan and contribute widely. We are doing it.
SGCNT_image_l.png

 

 * We can manufacture products with various shapes other than O-rings, so please feel free to contact us.



Chemical structure

4 Ethylene fluoride / perfluoroalkyl ether copolymer. Since all of the main chains are fluorine bonds (CF) and there are no hydrocarbon bonds (CH), they have extremely excellent chemical resistance and heat resistance. Since the structure is almost fluoride as a whole, it is difficult to crosslink , so CSM is added as an auxiliary leg.FP-FFSG.png
CSM: Cure Site Monomer

 Related laws and regulations

  • The content of 10 substances under the RoHS Directive (Pb, Cd, Hg, Cr6 +, PBB, PBDE, DEHP, BBP, DBP, DIBP) is below the threshold.

  • We do not intentionally add substances subject to REACH regulation.

  • We do not intentionally add TSCA PBT5 substances (DecaBDE, 2,4,6TTBP, PIP (3: 1), HCBD, PCTP).

Fluoropower FFSG (heat resistant FFKM / special grade) characteristic value and physical property value

Many of the high-performance rubber materials listed by manufacturers such as Fluoro- Power® and Kalrez®can be used interchangeably, but they are given special performance for specific purposes. Some of them are included. When handling it as an equivalent product, carefully check the conditions of use .

 Fluoropower FFSG and high temperature x long time (300 ° C x 670 hours) heat resistant aging test 

We conducted a heat-resistant aging test under special conditions (300 ° C x maximum 670 hours) for the top two grades of heat-resistant FFKM (Fluoropower FFSG and Fluoropower FFSW ) . The data is as follows.

 

Transition of hardness changeTransition of changes in tensile strengthChanges in growth
FP-FFSG Long-term heat resistance aging test (hardness) .pngFP-FFSG Long-term heat resistance aging test (tensile strength) .pngFP-FFSG Long-term heat-resistant aging test (elongation rate) .png
Legend (FP-FFSG, FP-FFSW) .png

 Fluoropower FFSG and temperature-specific ( 25 to 380 ° C) heat-resistant aging test

The data of the heat-resistant aging test (by temperature x 2 hours) conducted on the top two grades of heat-resistant FFKM (Fluoropower FFSG and Fluoropower FFSW ) are as follows.

 

Transition of hardness changeTransition of changes in tensile strengthChanges in growth
FP-FFSG_Temperature-specific heat aging test (hardness) .pngFP-FFSG_Temperature-specific heat aging test (tensile strength) .pngFP-FFSG_Heat-resistant aging test by temperature (elongation rate) .png
Legend (FP-FFSG, FP-FFSW) .png

Physical characteristics of Fluoropower FFSG

Test typeitem
Fluoropower FFSG
(measured value)
Normal physical characteristics testHardness (JIS A)85
Tensile strength (MPa)22.7
Growth rate(%)119
100% tensile stress (MPa)19.7
Heat resistant aging testTest condition300 ℃ x 70 hours
Change in hardness+4
Tensile strength change rate (%)-16
Growth rate of change (%)+52
Compression permanent strain testTest condition200 ℃ x 70 hours
Compression permanent distortion rate (%)34

 Operating temperature limit

The recommended value is 0 to 370 ° C. However, continuous use in the maximum temperature range tends to cause damage due to thermosetting, shortening the service life. Also, in the lowest temperature range , the rubber elasticity deteriorates, so the sealing performance deteriorates . be careful.

 Pressure characteristics

The recommended maximum pressure is 10MPa. However, the values will vary depending on the conditions. In addition, the pressure resistance is a combination of the backup ring can be improved by.

 chemical resistance

Extremely excellent. It is resistant to all chemicals and has outstanding performance among various rubber materials. Please refer to the table below for a list of durability against more liquids and gases in terms of chemical resistance (compatibility between contact fluid and material) of O-rings .

Drug nameResistanceDrug nameResistance
AcetaldehydeDimethylacetamide
acetoneDiethyl ether
Anilineheavy oil
Ammonia waterthinner
IPASpindle oil
ethanol100 ℃ steam
ethylene glycolTetrachlorethylene
EthylenediamineTetrahydrofuran
N-Methyl-2-pyrrolidonekerosene
Emulsion hydraulic oilTrichlorethylene
hydrochloric acidtoluene
Engine oilAnimal oil
aqua regiaButyl acetate
Hydrogen peroxide solutionHydrofluoric acid
Potassium hydroxideFreon R134a×
caustic sodaInactive fluorine oil×
gasolineBrake fluid
Cup greaseHexane
Gear oilbenzene
Xyleneformalin
Light oilMachine oil
Chloroformwater
KeroseneWater-based cutting oil
Acetic acidmethanol
Ethyl acetateMEK
nitric acidMethyl isobutyl ketone
Vegetable oilMonoethanolamine
Sodium hypochloritelacquer
DioxanePhosphoric acid ester-based hydraulic oil
Carbon tetrachlorideSulfuric acid
DichloromethaneLithium grease
Silicone greaseMineral oil-based refrigerating machine oil

◎: Can be used 〇: There is some influence △: Not recommended X: Cannot be used

Note) The above is reference data. Whether it can be used or not depends on the temperature, pressure, and other conditions.

 

About the use of Fluoropower FFSG (heat resistant FFKM / special grade)

Main usage points

  • Sealed parts of high temperature cylinders, pistons and rods

  • Sealing material for high temperature steam boilers

  • Chemical pump housing and connections

  • Chemical valves, high temperature valve stems and connections

  • Sealing material for high temperature vacuum equipment

  • Sealing material for high temperature fittings

  • Sealing material for mechanical seals

  • Sealing material for chemical plant equipment

  • Sealing material for chemical containers

  • CVD, diffusion process gate valve

  • CVD, diffusion process door valve

  • CVD, diffusion process L-shaped (angle) valve

  • CVD, diffusion process exhaust fittings

  • CVD, diffusion process peripherals

  • CVD, diffusion process chamber lid

 Handling precautions

  • Although it is a material that has excellent weather resistance and is not easily affected by light or heat, store it in a cool and dark place with low humidity just in case.

  • Please save it in a state where no load is applied. Deformation and cracking are likely to occur if stored in an stretched or compressed state.

  • Use above the recommended temperature and pressure will cause rapid deterioration. be careful.

  • Be careful not to come in contact with unsuitable fluids.



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